Liquid crystals can be radical
by Tyler Shendruk
Published: Oct 5
The problem
HEY, SCIENCE! WHY haven’t you built me an iPod the size of a single cell yet? I’m waiting.
Currently electronics are built out of bulk materials and have
inherent size limitations: A wire can only be carved so small if it’s
made from an everyday chunk of copper. But imagine if electronic
components could be made from large molecules or organics instead of
bulky metals.
One day, organic components might be smaller, cheaper, and even
easier to fabricate than traditional wires. Sure, it sounds like a great
idea, but is it possible?
The researcher
Alicea Leitch doesn’t know either, but she’s trying to find out.
Leitch is a post-doctoral researcher in the chemistry department at the
University of Ottawa who likes to work on projects that have concrete
applications.
Before she arrived at the University of Ottawa, Leitch had already
started working on highly reactive chemical substances called radicals.
The project
Radicals can be extremely reactive because they have an unpaired
electron, which is just dying to find its soulmate. It’s not exactly
picky—radicals will react with just about anything. However, when they
are stabilized, the unpaired electron can become very valuable.
Sometimes radicals can help carry charges, making otherwise
non-conductive materials more interesting.
This makes radicals tempting for molecular electronics.
Unfortunately, chemical stabilization almost always vetoes the
properties of interest.
The key
To control the radicals without loosing the conductivity, Leitch
doesn’t bother with chemical stabilization. Instead, she attaches the
radicals to microscopic discs so the previously troublesome unpaired
electron doesn’t belong to a single atom. It becomes shared between all
the atoms that make up the disc, making it less reactive but still
conductive.
On top of that, using discs has unexpected bonuses: They float in
liquid and they like to stack in an orderly fashion, like a crystal.
This makes them a liquid crystal. If Leitch can get the liquid crystals
just right, the discs will automatically assemble into tiny chains.
This natural stacking is great because the structure of molecular
electronic components plays a really important role, but is usually hard
to control. Because they are stacked together, the single electron can
jump from plate to plate, and eventually make its way from one end of
the chain to the other.
Together, the conductivity of the unpaired electron and the discs’
self-assembly into long, flexible chains could make Leitch’s liquid
crystals into pretty radical wires.